Intermediate of API

13080-86-9

  • Product Name:4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline (BAPP)
  • Molecular Formula:C27H26N2O2
  • Specifications:99%
  • Molecular Weight:410.516
Inquiry

Product Details;

CasNo: 13080-86-9

Molecular Formula: C27H26N2O2

High Purity 99% 4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline (BAPP) 13080-86-9 Powder Low Price

  • Molecular Formula:C27H26N2O2
  • Molecular Weight:410.516
  • Vapor Pressure:0-0Pa at 20-25℃ 
  • Melting Point:127-130 °C 
  • Boiling Point:587.1 °C at 760 mmHg 
  • PKA:5.16±0.10(Predicted) 
  • Flash Point:322.8 °C 
  • PSA:70.50000 
  • Density:1.178 g/cm3 
  • LogP:7.92390 

4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline(Cas 13080-86-9) Usage

Chemical Properties

4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline is white solid

Uses

It is applied in pharmaceutical industry.

13080-86-9 Relevant articles

Bis(azobenzene) diamines and photomechanical polymers made therefrom

-

, (2017/05/31)

Bis(azo-benzene) diamine monomers and a ...

Method for preparing 2,2-bis[4-(4-aminophenoxy)phenyl] propane

-

Paragraph 0026; 0027; 0030; 0031; 0035; 0037, (2017/08/28)

The invention belongs to the technical f...

Multivalent photo-crosslinkable coumarin-containing polybenzoxazines exhibiting enhanced thermal and hydrophobic surface properties

Lin, Ruey-Chorng,Mohamed, Mohamed Gamal,Hsu, Kuo-Chih,Wu, Jia-Yu,Jheng, Yu-Ru,Kuo, Shiao-Wei

, p. 10683 - 10696 (2016/02/09)

In this study, mono-, bi-, and trivalent...

Impact of backbone rigidity on the photomechanical response of glassy, azobenzene-functionalized polyimides

Wang, David H.,Wie, Jeong Jae,Lee, Kyung Min,White, Timothy J.,Tan, Loon-Seng

, p. 659 - 667 (2014/02/14)

Azobenzene-functionalized polyimide mate...

13080-86-9 Process route

2,2-bis[4-(4-nitrophenoxy)phenyl]propane
20653-11-6

2,2-bis[4-(4-nitrophenoxy)phenyl]propane

hydrazine hydrate
7803-57-8,79785-97-0

hydrazine hydrate

2,2-bis-{4-(4-aminophenoxy)phenyl}propane
13080-86-9,158066-25-2

2,2-bis-{4-(4-aminophenoxy)phenyl}propane

Conditions
Conditions Yield
2,2-bis[4-(4-nitrophenoxy)phenyl]propane; With palladium 10% on activated carbon; In ethanol; at 50 ℃; Reflux;
hydrazine hydrate; In ethanol; at 80 - 90 ℃; for 3h;
85%
BPA
80-05-7

BPA

2,2-bis-{4-(4-aminophenoxy)phenyl}propane
13080-86-9,158066-25-2

2,2-bis-{4-(4-aminophenoxy)phenyl}propane

Conditions
Conditions Yield
Multi-step reaction with 2 steps
1: Na2CO3
2: Zn, AcOH
With sodium carbonate; acetic acid; zinc;
Multi-step reaction with 2 steps
1: potassium carbonate; N,N-dimethyl-formamide / 12 h / Reflux
2: palladium 10% on activated carbon; hydrazine / ethanol; water / 12.5 h / 85 °C / Reflux
With palladium 10% on activated carbon; potassium carbonate; N,N-dimethyl-formamide; hydrazine; In ethanol; water;
Multi-step reaction with 2 steps
1: potassium carbonate / N,N-dimethyl-formamide / 24 h / 20 °C
2: palladium on activated charcoal; hydrogen / ethyl acetate / 24 h / 20 °C / 2844.39 Torr
With palladium on activated charcoal; hydrogen; potassium carbonate; In ethyl acetate; N,N-dimethyl-formamide;
Multi-step reaction with 2 steps
1.1: potassium carbonate / N,N-dimethyl-formamide / 48 h / 130 °C / Inert atmosphere
2.1: palladium 10% on activated carbon / ethanol / 2 h / 80 - 90 °C / Inert atmosphere
2.2: 48 h / Reflux
With palladium 10% on activated carbon; potassium carbonate; In ethanol; N,N-dimethyl-formamide;
Multi-step reaction with 2 steps
1: potassium carbonate / N,N-dimethyl-formamide / 24 h / 20 °C / Inert atmosphere
2: palladium on activated charcoal; hydrogen / ethyl acetate / 24 h / 20 °C / 2844.39 Torr
With palladium on activated charcoal; hydrogen; potassium carbonate; In ethyl acetate; N,N-dimethyl-formamide;

13080-86-9 Upstream products

  • 20653-11-6
    20653-11-6

    2,2-bis[4-(4-nitrophenoxy)phenyl]propane

  • 80-05-7
    80-05-7

    BPA

  • 100-00-5
    100-00-5

    4-chlorobenzonitrile

  • 350-46-9
    350-46-9

    4-Fluoronitrobenzene

13080-86-9 Downstream products

  • 1190053-16-7
    1190053-16-7

    BAA

  • 79922-55-7
    79922-55-7

    2,2'-bis-[4-(4-maleimidephenoxy)phenyl]propane

  • 1333382-36-7
    1333382-36-7

    C49H36N4O8

  • 1531603-34-5
    1531603-34-5

    2,2-bis{4-[4-(4-aminophenyldiazenyl)phenoxy]phenyl}propane