Intermediate of API

2142-68-9

  • Product Name：2'-Chloroacetophenone
  • Molecular Formula：C8H7ClO
  • Specifications：99%
  • Molecular Weight：154.596
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Product Details;

CasNo： 2142-68-9

Molecular Formula： C8H7ClO

Appearance： clear light yellow to amber liquid

Top Purity Pharmaceutical Intermediates 2'-Chloroacetophenone 2142-68-9 In Bulk Supply

  • Molecular Formula:C8H7ClO
  • Molecular Weight:154.596
  • Appearance/Colour:clear light yellow to amber liquid 
  • Melting Point:52-56 °C 
  • Refractive Index:n20/D 1.544  
  • Boiling Point:195.5 °C at 760 mmHg 
  • Flash Point:89.6 °C 
  • PSA：17.07000 
  • Density:1.163 g/cm3 
  • LogP:2.54260 

2'-Chloroacetophenone(Cas 2142-68-9) Usage

Chemical Properties

clear light yellow to amber liquid

Uses

2''-Chloroacetophenone (cas# 2142-68-9) is a compound useful in organic synthesis.

General Description

2′-Chloroacetophenone undergoes stereoselective reduction to (R)-2′-chloro-1-phenyl-ethanol by Saccharomyces cerevisiae B5. It is commonly used as lacrimator.

2142-68-9 Relevant articles

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Forbes,Mueller

, p. 488,498 (1957)

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A simple, efficient and recyclable copper(II) acetylacetonate catalytic system for oxidation of sec-alcohols in ionic liquid

Liu, Chong,Han, Jinyu,Wang, Juan

, p. 643 - 645 (2007)

A selective oxidation of secondary alcoh...

V2O5 anchored RuO2: An efficient nanocatalyst for aerial oxidation of alcohols

Ganesh Babu,Krishnamoorthi,Thiruneelakandan,Karvembu

, p. 1245 - 1252 (2014)

RuO2/V2O5 nanocatalyst has been prepared...

Ruthenium(II) carbonyl complexes with N-[di(alkyl/aryl)carbamothioyl] benzamide derivatives and triphenylphosphine as effective catalysts for oxidation of alcohols

Gunasekaran,Remya,Radhakrishnan,Karvembu

, p. 491 - 501 (2011)

Ruthenium(II) complexes, [RuCl(L)(CO)(PP...

An efficient and scalable room temperature aerobic alcohol oxidation catalyzed by iron chloride hexahydrate/mesoporous silica supported TEMPO

Wang, Lianyue,Li, Jun,Zhao, Xiaoping,Lv, Ying,Zhang, Hengyun,Gao, Shuang

, p. 6041 - 6045 (2013)

An efficient room temperature catalytic ...

Deep eutectic solvent supported TEMPO for oxidation of alcohols

Zhang, Yuecheng,Lü, Fenglian,Cao, Xiaohui,Zhao, Jiquan

, p. 40161 - 40169 (2014)

A novel deep eutectic solvent supported ...

-

Rogers

, p. 2784,2786 (1956)

-

Iron-catalyzed domino decarboxylation-oxidation of α,β-unsaturated carboxylic acids enabled aldehyde C-H methylation

Gong, Pei-Xue,Xu, Fangning,Cheng, Lu,Gong, Xu,Zhang, Jie,Gu, Wei-Jin,Han, Wei

, p. 5905 - 5908 (2021/06/18)

A practical and general iron-catalyzed d...

Highly ordered mesoporous hybrid silica functionalized with ionic liquid framework supported copper and its application in the oxidation of alcohols

Rajabi, Fatemeh,Bahrami, Nazli,Vessally, Esmail,Luque, Rafael

, (2021/10/27)

A highly ordered organic-inorganic hybri...

o-Quinone methide with overcrowded olefin component as a dehydridation catalyst under aerobic photoirradiation conditions

Uraguchi, Daisuke,Kato, Kohsuke,Ooi, Takashi

, p. 2778 - 2783 (2021/03/14)

Ano-quinone methide (o-QM) featuring an ...

Ruthenium(II) Complexes Bearing Schiff Base Ligands for Efficient Acceptorless Dehydrogenation of Secondary Alcohols?

Dong, Qing,Feng, Qi,Han, Zhangang,Hao, Zhiqiang,Lin, Jin,Liu, Kang,Lu, Guo-Liang,Ma, Dongzhu

, p. 121 - 128 (2020/12/25)

Four ruthenium(II) complexes 1—4 [RN=CH-...

2142-68-9 Process route

C<sub>14</sub>H<sub>28</sub>O<sub>7</sub>*C<sub>8</sub>H<sub>7</sub>N<sub>2</sub>O<sup>(1+)</sup>*BF<sub>4</sub><sup>(1-)</sup>

C14H28O7*C8H7N2O(1+)*BF4(1-)

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Conditions
Conditions Yield
In 1,2-dichloro-ethane; at 20 ℃; Rate constant; Kinetics; Thermodynamic data; var. crown ethers, ΔH(excit.), ΔS(excit.);

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