Chemical intermediate

345-92-6

  • Product Name:Bis(4-fluorophenyl)-methanone
  • Molecular Formula:C13H8F2O
  • Specifications:99%
  • Molecular Weight:218.203
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Product Details;

CasNo: 345-92-6

Molecular Formula: C13H8F2O

Appearance: white to slightly yellow crystalline powder

China cas 345-92-6 factory wholesale Bis(4-fluorophenyl)-methanone at affordable price

  • Molecular Formula:C13H8F2O
  • Molecular Weight:218.203
  • Appearance/Colour:white to slightly yellow crystalline powder 
  • Vapor Pressure:0.005Pa at 20℃ 
  • Melting Point:102-105 °C(lit.) 
  • Boiling Point:308.8 °C at 760 mmHg 
  • Flash Point:118.4 °C 
  • PSA:17.07000 
  • Density:1.239 g/cm3 
  • LogP:3.19580 

345-92-6 Relevant articles

Decatungstate-mediated solar photooxidative cleavage of CC bonds using air as an oxidant in water

Du, Dongdong,Luo, Junfei,Shi, Sanshan,Xie, Pan,Xue, Cheng

, p. 5936 - 5943 (2021/08/23)

With the increasing attention for green ...

Photo-induced oxidative cleavage of C-C double bonds for the synthesis of biaryl methanoneviaCeCl3catalysis

Xie, Pan,Xue, Cheng,Du, Dongdong,Shi, SanShan

supporting information, p. 6781 - 6785 (2021/08/20)

A Ce-catalyzed strategy is developed to ...

4,4 ’ - Difluorobenzophenone and preparation method and application thereof

-

, (2021/11/21)

The 4, 4 ’ difluorobenzophenone and the ...

Preparation method 4,4 ' -difluorobenzophenone and intermediate thereof

-

Paragraph 0068; 0073-0074; 0075; 0080-0081; 0082; ..., (2021/09/01)

The invention discloses 4-4' -difluorobe...

345-92-6 Process route

4,4'-difluorobenzhydryl alcohol
365-24-2

4,4'-difluorobenzhydryl alcohol

cyclohexanone
108-94-1,11119-77-0,9003-41-2,9075-99-4

cyclohexanone

hexahydro-2H-oxepin-2-one
502-44-3,24980-41-4,80137-66-2

hexahydro-2H-oxepin-2-one

4,4'-Difluorobenzophenone
345-92-6

4,4'-Difluorobenzophenone

Conditions
Conditions Yield
4,4'-difluorobenzhydryl alcohol; cyclohexanone; With N-hydroxyphthalimide; 2,2'-azobis(isobutyronitrile); oxygen; In ethyl acetate; at 75 ℃; for 22h;
With ammonium cerium (IV) nitrate; 1,1,1,3',3',3'-hexafluoro-propanol; In ethyl acetate; at 45 ℃; for 10h;
bis(methanesulfonyl)peroxide
1001-62-3

bis(methanesulfonyl)peroxide

4,4'-difluorodiphenylmethane
457-68-1

4,4'-difluorodiphenylmethane

4,4'-difluorobenzhydryl alcohol
365-24-2

4,4'-difluorobenzhydryl alcohol

4,4'-Difluorobenzophenone
345-92-6

4,4'-Difluorobenzophenone

Conditions
Conditions Yield
bis(methanesulfonyl)peroxide; 4,4'-difluorodiphenylmethane; With trimethylsilyl acetate; copper (I) acetate; In dichloromethane; at 23 ℃; for 12h; Inert atmosphere;
With sodium methylate; In methanol; at 23 ℃; for 8h;
34%
9%

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